Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3631
Title: A 2-pyridyl (py) attached phosphine imine [P(Npy)(NHpy)3] and an imido phosphinate ion [P(Npy)2(NHpy)2]− in its Ag(i) complex
Authors: GUPTA, ARVIND K.
Chipem, Francis A. S.
BOOMISHANKAR, RAMAMOORTHY
Dept. of Chemistry
Keywords: A 2-pyridyl
Phosphine imine
Phosphine imine
N-analogues of common phosphorus
Crystallography
Theoretical calculations
2012
Issue Date: Jan-2012
Publisher: Royal Society of Chemistry
Citation: Dalton Transactions, 41 (6), 1848-1853.
Abstract: A new phosphine imine 3, [P(Npy)(NHpy)3] (py = 2-pyridyl), was synthesized from the phosphonium salt 1, [P(NHpy)4]Cl. Subsequent reaction of 1 or 3 with AgClO4 lead to an unprecedented penta-nuclear Ag(I) complex 4 stabilized by two [P(Npy)2(NHpy)2]− anions [L]−. The packing diagram of 4 shows an interesting channel structure which contains solvated molecules of methanol and toluene. The diimine ligand [L]−, which represents the N-analogue of a phosphinate ion (H2PO4−), was obtained in situ under the mild reaction conditions in the absence of a base.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3631
https://doi.org/10.1039/C1DT12004B
ISSN: 1477-9226
1477-9234
Appears in Collections:JOURNAL ARTICLES

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