Please use this identifier to cite or link to this item:
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3642| Title: | A Homochiral Luminescent 2D Porous Coordination Polymer with Collagen-Type Triple Helices Showing Selective Guest Inclusion |
| Authors: | JOARDER, BIPLAB Chaudhari, Abhijeet K. GHOSH, SUJIT K. Dept. of Chemistry |
| Keywords: | Homochiral luminescent Porous coordination polymer Cadmium Water and methanol 2012 |
| Issue Date: | Mar-2012 |
| Publisher: | American Chemical Society |
| Citation: | Inorganic Chemistry, 51 (8), 4644-4649. |
| Abstract: | A homochiral luminescent porous coordination polymer, [Cd(L)(H2O)]·3H2O, with interconnected collagen like triple-helical chains has been synthesized solvothermally by using cadmium(II) salt and a newly designed d-isosorbide-based, enantiomerically pure chiral ligand. The framework is a 2D porous material and forms a 1D channel along the a axis, with the channel dimensions ∼6.2 × 4.4 Å2. The compound has high selectivity in the uptake of water and methanol over other solvents (e.g., tetrahydrofuran, ethanol, benzene, and cyclohexane) inside the channels. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3642 https://doi.org/10.1021/ic2025389 |
| ISSN: | 0020-1669 1520-510X |
| Appears in Collections: | JOURNAL ARTICLES |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.