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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3656| Title: | Regioselective Ortho-Arylation and Alkenylation of N-Alkyl Benzamides with Boronic Acids via Ruthenium-Catalyzed C-H Bond Activation: An Easy Route to Fluorenones Synthesis |
| Authors: | Chinnagolla, Ravi Kiran JEGANMOHAN, MASILAMANI Dept. of Chemistry |
| Keywords: | Regioselective Easy Route Fluorenones Synthesis Boronic Acids C-H Bond Activation 2012 |
| Issue Date: | Oct-2012 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 1 4 (20), 5246-5249. |
| Abstract: | A highly regioselective ruthenium-catalyzed ortho-arylation of substituted N-alkyl benzamides with aromatic boronic acids in the presence of [{RuCl2(p-cymene)}2], AgSbF6, and Ag2O is described. Further, ortho-arylated N-alkyl benzamides were converted into fluorenones in the presence of trifluoroacetic anhydride and HCl. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3656 https://doi.org/10.1021/ol3024067 |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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