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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3987| Title: | Imido-P(V) trianion supported enantiopure neutral tetrahedral Pd(II) cages |
| Authors: | RAJASEKAR, PRABHAKARAN Pandey, Swechchha PAITHANKAR, HARSHAD CHUGH, JEETENDER Steiner, Alexander BOOMISHANKAR, RAMAMOORTHY Dept. of Chemistry |
| Keywords: | Imido-P(V) Trianion Supported enantiopure Neutral tetrahedral Pd(II) cages 2018 |
| Issue Date: | Jan-2018 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 54(15), 1873-1876. |
| Abstract: | Charge-neutral chiral hosts are attractive due to their ability to recognize a wide range of guest functionalities and support enantioselective processes. However, reports on such charge-neutral cages are very scarce in the literature. Here, we report an enantiomeric pair of tetrahedral Pd(II) cages built from chiral tris(imido)phosphate trianions and oxalate linkers, which exhibit enantioselective separation capabilities for epichlorohydrin, β-butyrolactone, and 3-methyl- and 3-ethyl cyclopentanone. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3987 https://doi.org/10.1039/C8CC00207J |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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