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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4198| Title: | Transition-Metal-Free Addition Reaction for the Synthesis of 3-(Aminobenzylidene/aminoalkylidene)indolin-2-ones and Its Synthetic Applications |
| Authors: | BISHT, GIRISH SINGH GNANAPRAKASAM, BOOPATHY Dept. of Chemistry |
| Keywords: | Beta-Dicarbonyl|Compounds One-Pot Synthesis C Double-Bond Heterocyclic Synthesis Oxidative Cleavage Coupling TOC-NOV-2019 2019 |
| Issue Date: | Sep-2019 |
| Publisher: | American Chemical Society |
| Citation: | Journal of Organic Chemistry, 84(21), 13516-13527. |
| Abstract: | A novel and efficient transition-metal-free approach for the exclusive synthesis of Z-3-(aminobenzylidene/aminoalkylidene)indolin-2-ones in high yield from 2-oxindole and aryl/alkyl nitrile in the presence of LiOtBu and 2,2?-bipyridine system is described. In addition, we disclosed a new approach towards the metal-free fluorination using selectfluor and the C?C bond cleavage using CuI and environmentally benign O2. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4198 https://doi.org/10.1021/acs.joc.9b01771 |
| ISSN: | 1520-6904 |
| Appears in Collections: | JOURNAL ARTICLES |
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