Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages

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Title:	Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages
Authors:	KUMAR, KILAPARTHI SRAVAN Mane, Vishwanath S. YADAV, ASHOK Kumbhar, Avinash S. BOOMISHANKAR, RAMAMOORTHY Dept. of Chemistry
Keywords:	Metal-Organic Frameworks Complexes Nickel Catalysts Electrocatalyst Generation Challenges TOC-NOV-2019 2019
Issue Date:	Oct-2019
Publisher:	Royal Society of Chemistry
Citation:	Chemical Communications, 55(87), 13156-13159.
Abstract:	A self-assembled M6L8 type cage-connected 1D-coordination network of formula {[Ni6(MeSi(3py)3)8Cl9(H2O)2]Cl3·16H2O}∞ (1) was obtained from a 3-pyridyl substituted silane ligand MeSi(3py)3. This complex shows significantly high performance for the electrocatalytic and photocatalytic hydrogen evolution reaction (HER) in water. A maximum turnover number (TON) of 2824 has been observed for photocatalytic HER after 69 h.
URI:	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4216 https://doi.org/10.1039/C9CC06286F
ISSN:	1359-7345 1364-548X
Appears in Collections:	JOURNAL ARTICLES

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