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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4304| Title: | Oxidative decarboxylation of arylacetic acids in water: One-pot transition-metal-free synthesis of aldehydes and ketones |
| Authors: | METE, TRIMBAK B. KHOPADE, TUSHAR M. BHAT, RAMAKRISHNA G. Dept. of Chemistry |
| Keywords: | Aldehydes and ketones Transition-metal free Water Persul fate One-pot synthesis Decarboxylation 2017 |
| Issue Date: | Jul-2017 |
| Publisher: | Elsevier B.V. |
| Citation: | Tetrahedron Letters, 58(29), 2822-2825. |
| Abstract: | One-pot transition-metal-free synthesis of aromatic aldehydes and ketones via oxidative decarboxylation of arylacetic acids in water is developed. Protocol relies on the direct decarboxylation of sp3-hybridized carbon in water without any over oxidation into carboxylic acids with minimal waste. Reaction mechanism is investigated and application of this protocol is demonstrated on a gram scale. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4304 https://doi.org/10.1016/j.tetlet.2017.06.013 |
| ISSN: | 0040-4039 |
| Appears in Collections: | JOURNAL ARTICLES |
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