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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4370| Title: | N-heterocyclic silylene stabilized monocordinated copper(i)-arene cationic complexes and their application in click chemistry |
| Authors: | PARVIN, NASRINA HOSSAIN, JABED George, Anjana Parameswaran, Pattiyil KHAN, SHABANA Dept. of Chemistry |
| Keywords: | Silicon(II) BIS(Trimethylsilyl)Amide Copper; Bis(Silylene) Reactivity Efficient Carbene Silver CU TOC-JAN-2020 2020 |
| Issue Date: | Jan-2020 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 56(2), 273-276. |
| Abstract: | Herein for the first time we report monocoordinated cationic Cu(i) complexes with unsymmetrical arenes (toluene and m-xylene) [LCu(eta(3)-C7H8)](+)[SbF6](-) and [{LCu(eta(2)-Me2C6H4)}](+)[SbF6](-) [L = {PhC(NtBu)(2)SiN(SiMe3)(2)}], [IPr (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)], their reactivity and catalytic applications in CuAAC reactions (12 examples). The bonding analysis was performed in both silylene and carbene complexes using the EDA-NOCV method at the BP86/TZ2P level of theory. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4370 https://doi.org/10.1039/c9cc09115g |
| ISSN: | 1364-548X 1359-7345 |
| Appears in Collections: | JOURNAL ARTICLES |
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