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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4926| Title: | N-Heterocyclic silylene/germylene ligands in Au(i) catalysis |
| Authors: | PARVIN, NASRINA MISHRA, BIJOYANANDA George, Anjana NERALKAR, MAHESH HOSSAIN, JABED Parameswaran, Pattiyil HOTHA, SRINIVAS KHAN, SHABANA Dept. of Chemistry |
| Keywords: | Silicon(II) Bis(Trimethylsilyl)Amide Gold(I) Complexes Cyanovirin-N Carbene Activation AG Phosphine TOC-JUL-2020 2020 2020-JUL-WEEK5 Ethylene Silylene Donors |
| Issue Date: | Jul-2020 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 56(55), 7625-7628. |
| Abstract: | Cationic Au(I) complexes (2, 5 and 8) supported by N-heterocyclic carbene, silylene and germylene ligands were prepared and their potential as catalysts in glycosidation chemistry has been evaluated. Insights into the mechanism are provided using DFT studies. Practical application of them as catalysts was achieved by the synthesis of the branched pentamannan core of the HIV-gp120 envelope under mild conditions. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/4926 https://doi.org/10.1039/D0CC03156A |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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