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Title: | Zn7O2(RCOO)(10) Clusters and Nitro Aromatic Linkers in a Porous Metal-Organic Framework |
Authors: | Iremonger, Simon S. VAIDHYANATHAN, RAMANATHAN Mah, Roger K. Shimizu, George K. H. Dept. of Chemistry |
Keywords: | Secondary Building Units Carbon-Dioxide Capture Coordination Polymers Crystal-Structures Water-Adsorption Surface-Area CO2 Complexes Chemistry Molecule 2013 |
Issue Date: | Mar-2013 |
Publisher: | American Chemical Society |
Citation: | Inorganic Chemistry, 52(8), 4124-4126. |
Abstract: | A new metal–organic framework, CALF-22 comprising Zn7O2(COO)10 secondary building units and 2-nitro-1,4-benzenedicarboxylate, is reported. The porosity and gas adsorption of N2, H2, CO2, and CH4 are studied, and CALF-22 has a surface area in excess of 1000 m2/g. The stability of the larger zinc cluster and the effect of the nitro group on gas sorption are also studied. |
URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5186 https://doi.org/10.1021/ic302127y |
ISSN: | 0020-1669 |
Appears in Collections: | JOURNAL ARTICLES |
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