Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5186
Title: Zn7O2(RCOO)(10) Clusters and Nitro Aromatic Linkers in a Porous Metal-Organic Framework
Authors: Iremonger, Simon S.
VAIDHYANATHAN, RAMANATHAN
Mah, Roger K.
Shimizu, George K. H.
Dept. of Chemistry
Keywords: Secondary Building Units
Carbon-Dioxide Capture
Coordination Polymers
Crystal-Structures
Water-Adsorption
Surface-Area
CO2
Complexes
Chemistry
Molecule
2013
Issue Date: Mar-2013
Publisher: American Chemical Society
Citation: Inorganic Chemistry, 52(8), 4124-4126.
Abstract: A new metal–organic framework, CALF-22 comprising Zn7O2(COO)10 secondary building units and 2-nitro-1,4-benzenedicarboxylate, is reported. The porosity and gas adsorption of N2, H2, CO2, and CH4 are studied, and CALF-22 has a surface area in excess of 1000 m2/g. The stability of the larger zinc cluster and the effect of the nitro group on gas sorption are also studied.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5186
https://doi.org/10.1021/ic302127y
ISSN: 0020-1669
Appears in Collections:JOURNAL ARTICLES

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