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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5867| Title: | The diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene |
| Authors: | PARVIN, NASRINA SEN, NILANJANA Muhasina, Puthan Veetil Tothadi, Srinu Parameswaran, Pattiyil KHAN, SHABANA Dept. of Chemistry |
| Keywords: | Chemistry 2021-MAY-WEEK2 TOC-MAY-2021 2021 |
| Issue Date: | May-2021 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications, 57(41), 5008-5011. |
| Abstract: | The reactivity of NOBF4 towards silylene, disilene, germylene, stannylenes has been described. Smooth syntheses of compounds of composition [PhC(NtBu)(2)E(= O -> BF3)N(SiMe3)(2), E = Si (3) and Ge (4)] were accomplished from the corresponding tetrylenes. An unusual heterocycle (10) featuring B, Sn, N, P, and O atoms was obtained from the reaction with a stannylene, while a 1,2-vicinal anti addition of fluoride was observed with a disilene (12). |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5867 https://doi.org/10.1039/d1cc01034d |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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