Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5990
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dc.contributor.authorSamantaray, Manoja K.en_US
dc.contributor.authorMISHRA, SANDEEP K.en_US
dc.contributor.authorSaidi, Ayaen_US
dc.contributor.authorBasset, Jean-Marieen_US
dc.date.accessioned2021-06-30T09:19:11Z
dc.date.available2021-06-30T09:19:11Z
dc.date.issued2021-07en_US
dc.identifier.citationJournal of Organometallic Chemistry, 945, 121864.en_US
dc.identifier.issn0022-328Xen_US
dc.identifier.issn1872-8561en_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5990
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2021.121864en_US
dc.description.abstractSurface organometallic chemistry (SOMC) is an established concept, associated with specific tools for the characterization of a well-defined single-site catalysts. Primarily, chemical industry preferred heterogeneous catalyst over homogeneous catalyst for various reasons. But the difficulty in development of a well-defined heterogeneous catalyst stalled by the presence of various kinds of active sites as well as their low concentration on surfaces. To develop a well-defined heterogeneous catalyst which can possess hundred percent active sites like that of homogeneous catalyst a new branch was developed called surface organometallic catalyst (SOMCcat). This is a well-proven concept where a homogeneous catalyst could graft on an oxide support to form SOMCcat. These surface species can be well-characterized by modern NMR techniques apart from EXAFS, IR, and gas quantification methods. In this review the application of SOMC strategy for the design and preparation of catalyst for industrial relevant processes are discussed.en_US
dc.language.isoenen_US
dc.publisherElsevier B.V.en_US
dc.subjectSurface organometallic complexesen_US
dc.subjectCarbynesen_US
dc.subjectCarbenesen_US
dc.subjectMetal-hydridesen_US
dc.subjectMetal-alkylsen_US
dc.subject2021-JUN-WEEK5en_US
dc.subjectTOC-JUN-2021en_US
dc.subject2021en_US
dc.titleSurface organometallic chemistry: A sustainable approach in modern catalysisen_US
dc.typeArticleen_US
dc.contributor.departmentDept. of Physicsen_US
dc.identifier.sourcetitleJournal of Organometallic Chemistryen_US
dc.publication.originofpublisherForeignen_US
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