Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6055
Title: Direct access to α-acyloxycarbonyl compounds and esters via oxidative esterification of aldehydes under visible light
Authors: BHOWMICK, ANINDITA
WARGHUDE, PRAKASH K.
DHARPURE, PANKAJ D.
BHAT, RAMAKRISHNA G.
Dept. of Chemistry
Keywords: Antifungal Miconazole Activity
Acid
Acyloxylation
Alkenes
Oxo
Transformation
Analgesics
Conversion
Acylation
Arylation
Chemistry
2021-JUL-WEEK1
TOC-JUL-2021
2021
Issue Date: Sep-2021
Publisher: Royal Society of Chemistry
Citation: Organic Chemistry Frontiers, 8(17), 4777-4784.
Abstract: Herein we report the efficient synthesis of α-acyloxycarbonyl compounds and esters starting directly from aldehydes and α-bromocarbonyl compounds/benzyl bromide derivatives and bromo nitriles using an organic photocatalyst in combination with silver tetrafluoroborate under visible light at room temperature. The reaction is compatible with a variety of functional groups and has been successfully applied to the synthesis of various molecules. The strength of this protocol was effectively demonstrated by utilising both aromatic and aliphatic aldehydes. The detailed controlled studies including the labeling experiment and fluorescence spectroscopic data clearly revealed the reductive quenching of the photoredox catalytic cycle.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6055
https://doi.org/10.1039/D1QO00731A
ISSN: 2052-4129
Appears in Collections:JOURNAL ARTICLES

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