Synthesis and Application of Silylene-Stabilized Low-Coordinate Ag(I) Arene Cationic Complexes

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Title:	Synthesis and Application of Silylene-Stabilized Low-Coordinate Ag(I) Arene Cationic Complexes
Authors:	PARVIN, NASRINA SEN, NILANJANA TOTHADI, SRINU Muhammed, Shahila Parameswaran, Pattiyil KHAN, SHABANA Dept. of Chemistry
Keywords:	Chemistry 2021-JUL-WEEK3 TOC-JUL-2021 2021
Issue Date:	Jun-2021
Publisher:	American Chemical Society
Citation:	Organometallics, 40(11), 1626-1632.
Abstract:	We report the first examples of N-heterocyclic silylene-stabilized monocoordinate Ag(I) cationic complexes weakly bound to the free arene rings (C6H6, C6Me6, and C7H8). Further, the application of these electrophilic Ag(I) complexes as catalysts has been investigated toward A3-coupling reactions, which afforded a series of propargylamines in good to excellent yields with low catalyst loading under a solvent-free condition (19 examples).
URI:	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6093 https://doi.org/10.1021/acs.organomet.1c00083
ISSN:	0276-7333 1520-6041
Appears in Collections:	JOURNAL ARTICLES

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