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DC Field | Value | Language |
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dc.contributor.author | SHAIKH, MOSEEN A. | en_US |
dc.contributor.author | UBALE, AKASH S. | en_US |
dc.contributor.author | GNANAPRAKASAM, BOOPATHY | en_US |
dc.date.accessioned | 2021-09-27T07:06:51Z | |
dc.date.available | 2021-09-27T07:06:51Z | |
dc.date.issued | 2021-11 | en_US |
dc.identifier.citation | Advanced Synthesis & Catalysis, 363(21), 4876-4882. | en_US |
dc.identifier.issn | 1615-4169 | en_US |
dc.identifier.uri | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6282 | |
dc.identifier.uri | https://doi.org/10.1002/adsc.202100793 | en_US |
dc.description.abstract | Indium-catalyzed sequential remote C−H functionalization (C-6 position) and C3-indolylation of peroxyoxindole using indole is described for the synthesis of terindolinone derivatives. Whereas, N-substituted 3-phenyl peroxyoxindole derivatives undergoes consecutive skeletal rearrangement to generate transient carbocation, which has been trapped with indole nucleophile to generate 2-(1H-indol-3-yl)-4-alkyl-benzo[b][1,4]oxazin-3(4H)-one derivatives. In contrast with Indium (III) Chloride, FeCl3 ⋅ 6H2O facilitates oxidative cleavage of the peroxyoxindole (Hock cleavage) and further reaction with indole to afford biologically important trisindoline derivatives. A plausible mechanism has been proposed for these reactions with experimental evidences. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley | en_US |
dc.subject | Chemistry | en_US |
dc.subject | 2021-SEP-WEEK3 | en_US |
dc.subject | TOC-SEP-2021 | en_US |
dc.subject | 2021 | en_US |
dc.title | Indium Catalyzed Sequential Regioselective Remote C−H Indolylation and Rearrangement Reaction of Peroxyoxindole | en_US |
dc.type | Article | en_US |
dc.contributor.department | Dept. of Chemistry | en_US |
dc.identifier.sourcetitle | Advanced Synthesis & Catalysis | en_US |
dc.publication.originofpublisher | Foreign | en_US |
Appears in Collections: | JOURNAL ARTICLES |
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