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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6283| Title: | Ru-MACHO-Catalyzed Direct Inter/Intramolecular Macrocyclization of Alcohols and Ketones |
| Authors: | JAMDADE, AKASH BANDU SUTAR, DASHRAT VISHAMBAR BISHT, GIRISH SINGH GNANAPRAKASAM, BOOPATHY Dept. of Chemistry |
| Keywords: | Chemistry 2021-SEP-WEEK3 TOC-SEP-2021 2021 |
| Issue Date: | Oct-2021 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 23(19), 7386–7390. |
| Abstract: | Herein we describe a new approach for end-to-end cyclization to construct macrocycles through the inter/intramolecular dehydrogenative coupling of alcohols and ketones in the presence of a Ru-MACHO catalyst. This method is highly atom economical and sustainable and can be used for many substrates. Additionally, this method results in the generation of only water as the byproduct. Moreover, in this approach, high dilution of the reactants is crucial for cyclization and high-yield macrocycle synthesis. |
| URI: | https://doi.org/10.1021/acs.orglett.1c02569 http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6283 |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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