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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6346| Title: | Stimuli-Responsive Anion Transport through Acylhydrazone-Based Synthetic Anionophores |
| Authors: | AHMAD, MANZOOR CHATTOPADHAYAY, SANDIP MONDAL, DEBASHIS Vijayakanth, Thangavel TALUKDAR, PINAKI Dept. of Chemistry |
| Keywords: | Artificial Ion Channels Chloride Transport Potassium Channels Apoptosis Assemblies Molecules Efficient Switches Dynamics Pyridyl 2021-OCT-WEEK3 TOC-OCT-2021 2021 |
| Issue Date: | Oct-2021 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 23(19), 7319–7324. |
| Abstract: | Photoswitchable acylhydrazone-based synthetic anionophores are reported. Single-crystal X-ray structure and 1H NMR titration studies confirmed the chloride binding in solid and solution states. The ion transport activity of 1a was greatly attenuated through a phototriggered E to Z photoisomerization process, and the photoisomerized deactivated state showed high kinetic stability due to an intramolecular hydrogen bond. Switchable “OFF–ON” transport activity was achieved by the application of light and acid-catalyzed reactivation process. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6346 https://doi.org/10.1021/acs.orglett.1c02249 |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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