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Title: | Reversible redox switching between local and global aromaticity for core-modified expanded carbaisophlorinoids |
Authors: | AMBHORE, MADAN D. PANCHAL, SANTOSH P. Mondal, Arpan Konar, Sanjit ANAND, V. G. Dept. of Chemistry |
Keywords: | Porphyrin States 2022-APR-WEEK1 TOC-APR-2022 2022 |
Issue Date: | Mar-2022 |
Publisher: | Royal Society of Chemistry |
Citation: | Organic & Biomolecular Chemistry |
Abstract: | Two dithienothiophene based 28π antiaromatic macrocycles with benzene and azulene units and their effects on local and global (anti)aromaticity have been described. Experimental and computational studies confirmed the presence of weak paratropic and strong diatropic ring current effects in neutral and dicationic states, respectively. |
URI: | https://doi.org/10.1039/D1OB02230J http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/6745 |
ISSN: | 1477-0520 1477-0539 |
Appears in Collections: | JOURNAL ARTICLES |
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