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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7249| Title: | Dehydrogenative Intramolecular Macrolactonization of Dihydroxy Compounds Using Ru-MACHO Catalyst |
| Authors: | JAMDADE, AKASH BANDU SUTAR, DASHRAT VISHAMBAR GNANAPRAKASAM, BOOPATHY Dept. of Chemistry |
| Keywords: | Alcohols Catalysts Chemical reactions Hydrocarbons Hydrogen 2022-JUL-WEEK2 TOC-JUL-2022 2022 |
| Issue Date: | Jun-2022 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters, 24(24), 4394–4398. |
| Abstract: | Herein, we have developed a new approach for the synthesis of 11 to 21-membered macrolactones via intramolecular dehydrogenative coupling of primary alcohols by using Ru-MACHO as a catalyst and Cs2CO3 as a base. This protocol generated 11–21-ring-sized macrocycles (26 derivatives), free from an external oxidant or an additive, eliminating stoichiometric reagents and producing only hydrogen as a byproduct. |
| URI: | https://doi.org/10.1021/acs.orglett.2c01617 http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7249 |
| ISSN: | 1523-7052 1523-7060 |
| Appears in Collections: | JOURNAL ARTICLES |
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