1. Digital Repository at Indian Institute of Science Education and Research Pune
  2. PUBLICATIONS & PATENTS
  3. JOURNAL ARTICLES
Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7355
Full metadata record
DC FieldValueLanguage
dc.contributor.authorSEN, NILANJANAen_US
dc.contributor.authorGOTHE, PRACHIen_US
dc.contributor.authorSarkar, Pallavien_US
dc.contributor.authorDas, Shubhajiten_US
dc.contributor.authorTothadi, Srinuen_US
dc.contributor.authorPati, Swapan K.en_US
dc.contributor.authorKHAN, SHABANAen_US
dc.date.accessioned2022-09-13T10:42:14Z
dc.date.available2022-09-13T10:42:14Z
dc.date.issued2022-09en_US
dc.identifier.citationChemical Communications, 58(74), 10380-10383.en_US
dc.identifier.issn1359-7345en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.urihttps://doi.org/10.1039/D2CC03158Ben_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7355
dc.description.abstractThe synthesis of novel stibenium cations and their catalytic application in cyanosilylation of carbonyl compounds have been described. Treatment of chlorostibine L1SbCl [L1 = 1,2-C6H4{N(CH2tBu)}2] (2) with 1 equiv. of AgOTf and AgSbF6 resulted in the formation of donor free L1SbOTf (3) and [L1Sb]+[SbF6]− (4), respectively. Among these three compounds, 4 exhibits excellent catalytic activity towards the cyanosilylation of aldehydes and ketones.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectPnictogenium Cationsen_US
dc.subjectLewis Acidityen_US
dc.subjectHydroborationen_US
dc.subjectActivationen_US
dc.subjectHydrosilylationen_US
dc.subjectChemistryen_US
dc.subjectGermyleneen_US
dc.subjectAntimonyen_US
dc.subjectComplexen_US
dc.subject2022-SEP-WEEK1en_US
dc.subjectTOC-SEP-2022en_US
dc.subject2022en_US
dc.titleDonor free stibenium cation as an efficient cyanosilylation catalysten_US
dc.typeArticleen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.identifier.sourcetitleChemical Communicationsen_US
dc.publication.originofpublisherForeignen_US
Appears in Collections:JOURNAL ARTICLES

Files in This Item:
There are no files associated with this item.
Show simple item record


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.