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Title: | Luminescent magnesium complexes with intra- and inter-ligand charge transfer |
Authors: | Kumar, Rohit Pahar, Sanjukta CHATTERJEE, JOY Dash, Soumya Ranjan Gonnade, Rajesh G. Vanka, Kumar Sen, Sakya S Dept. of Chemistry |
Keywords: | Electronic-structure Photochemistry Photophysics Mechanism 2022-OCT-WEEK2 TOC-OCT-2022 2022 |
Issue Date: | Oct-2022 |
Publisher: | Royal Society of Chemistry |
Citation: | Chemical Communications, 58(84), 11843-11846. |
Abstract: | Herein, we report two 2,2′-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively. Theoretical calculations reveal that their emissive properties originate from the intra- and inter-ligand charge transfer. |
URI: | https://doi.org/10.1039/D2CC04142A http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7411 |
ISSN: | 1359-7345 1364-548X |
Appears in Collections: | JOURNAL ARTICLES |
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