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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | SHIRAJ, ABDUL | en_US |
| dc.contributor.author | Ramabhadran, Raghunath O. | en_US |
| dc.contributor.author | GANESH, KRISHNA N. | en_US |
| dc.date.accessioned | 2022-12-28T09:21:55Z | - |
| dc.date.available | 2022-12-28T09:21:55Z | - |
| dc.date.issued | 2022-10 | en_US |
| dc.identifier.citation | Organic Letters, 24(40), 7421–7427. | en_US |
| dc.identifier.issn | 1523-7060 | en_US |
| dc.identifier.issn | 1523-7052 | en_US |
| dc.identifier.uri | https://doi.org/10.1021/acs.orglett.2c02993 | en_US |
| dc.identifier.uri | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/7542 | - |
| dc.description.abstract | The replacement of α(CH2) by NH in monomers of standard aeg PNA and its homologue β-ala PNA leads to respective aza-PNA monomers (1 and 2) in which the NαH can form either an 8-membered H-bonded ring with folding of the backbone (DMSO and water) or a 5-membered NαH─αCO (water) to stabilize E-type rotamers. Such aza-PNA oligomers with exclusive E rotamers and intraresidue backbone H-bonding can modulate its DNA/RNA binding and assembling properties. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.subject | Amides | en_US |
| dc.subject | Chemical structure | en_US |
| dc.subject | Nuclear magnetic resonance spectroscopy | en_US |
| dc.subject | Organic compounds | en_US |
| dc.subject | Solvents | en_US |
| dc.subject | 2022-DEC-WEEK3 | en_US |
| dc.subject | TOC-DEC-2022 | en_US |
| dc.subject | 2022 | en_US |
| dc.title | Aza-PNA: Engineering E-Rotamer Selectivity Directed by Intramolecular H-bonding | en_US |
| dc.type | Article | en_US |
| dc.contributor.department | Dept. of Chemistry | en_US |
| dc.identifier.sourcetitle | Organic Letters | en_US |
| dc.publication.originofpublisher | Foreign | en_US |
| Appears in Collections: | JOURNAL ARTICLES | |
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