Please use this identifier to cite or link to this item: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/8031
Title: A path integral approach to quantum fluid dynamics: application to double well potential
Authors: GHOSH, SAGNIK
Ghosh, Swapan K.
Dept. of Physics
Keywords: Quantum fluid dynamics
Quantum potential
Path integral
Quantum trajectories
Double well potential
Anharmonic oscillator
2023-JUN-WEEK1
TOC-JUN-2023
2023
Issue Date: Jun-2023
Publisher: Springer Nature
Citation: Theoretical Chemistry Accounts, 142, 57.
Abstract: In this work we develop an alternative approach for solution of Quantum Trajectories using the Path Integral method. The state-of-the-art technique in the field is to solve a set of nonlinear, coupled partial differential equations simultaneously. We opt for a fundamentally different route. We first derive a general closed form expression for the Path Integral propagator valid for any general potential as a functional of the corresponding classical path. The method is exact and is applicable in many dimensions as well as multi-particle cases. This, then, is used to compute the Quantum Potential, which, in turn, can generate the Quantum Trajectories. As a model application to illustrate the method, we solve for the double-well potential, both analytically (using a perturbative approach) and numerically (exact solution). Using this we delve into seeking insight into Quantum Tunnelling. The work formally bridges the Path Integral approach with Quantum Fluid Dynamics, an issue of fundamental importance.
URI: https://doi.org/10.1007/s00214-023-02995-w
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/8031
ISSN: 1432-2234
1432-881X
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