Please use this identifier to cite or link to this item:
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/8789| Title: | A Formal Synthesis of (-)-Brasilenol |
| Other Titles: | A Formal Synthesis of (-)-Brasilenol from Chiral Pool |
| Authors: | Kaliappan, Krishna CHAUHAN, TIRTH Dept. of Chemistry 20191159 |
| Keywords: | Natural Product Formal Synthesis Brasilenol Chiral Pool |
| Issue Date: | May-2024 |
| Citation: | 48 |
| Abstract: | Our efforts towards a chiral pool synthesis of (-)-brasilenol from (-)-β-pinene is reported here. Starting from relatively abundant (-)-β-pinene, the unnatural enantiomer (-)-brasilenol was targeted in 11 steps. Use of stereospecific ring-opening was employed to ensure conservation of stereocenter at the isopropyl group, while hydrogenative stereospecific isomerization of exocyclic enone to endocyclic enone was utilized for prevention of racemization of the methyl group. |
| URI: | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/8789 |
| Appears in Collections: | MS THESES |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 20191159_Tirth_Chauhan_MS_Thesis.pdf | MS Thesis | 2.49 MB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.