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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/9060| Title: | A hybrid silylene-Pd catalyst: efficient C-N cross-coupling of sterically bulky amines and chiral amines |
| Authors: | KAULAGE, SANDEEP H. PARVIN, NASRINA Khopade, Kishor V. KHAN, SHABANA Dept. of Chemistry |
| Keywords: | Arylation Ligand Amination 2024-AUG-WEEK2 TOC-AUG-2024 |
| Issue Date: | Aug-2024 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Chemical Communications |
| Abstract: | Herein, we report a catalytic system with N-heterocyclic silylene (NHSi)-phosphine-based hybrid bidentate ligands [PhC(NtBu)2SiN(PR2)(2,6-iPr2-C6H3)] and Pd(dba)2, which serves as an effective catalyst for C–N cross-coupling of a wide range of sterically bulky amines and optically active amines, which is challenging otherwise. |
| URI: | https://doi.org/10.1039/D4CC03108C http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/9060 |
| ISSN: | 1359-7345 1364-548X |
| Appears in Collections: | JOURNAL ARTICLES |
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