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http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/9375| Title: | Visible Light-Induced Sequential Nitrogen Insertion and Benzotriazolation of Quinoxaline-2(1H)-ones |
| Authors: | MONDAL, SHANKHAJIT MALODE, AKHILESH NARENDRA LONDHE, GOKUL S. GNANAPRAKASAM, BOOPATHY Dept. of Chemistry |
| Keywords: | Chemical reactions Electromagnetic radiation Irradiation Nitrogen Photochemical reactions 2025-FEB-WEEK1 TOC-FEB-2025 2025 |
| Issue Date: | Feb-2025 |
| Publisher: | American Chemical Society |
| Citation: | Organic Letters |
| Abstract: | Herein, we report a visible light-mediated sequential reaction involving in situ generation of benzotriazole from benzene-1,2-diamine and tert-butyl nitrite via nitrogen insertion and concomitant cross-coupling with quinoxaline-2(1H)-ones via C–N bond formation in one pot. This protocol uses metal-free mild conditions and demonstrated 36 examples of ≤80% yield with wide functional group tolerance. |
| URI: | https://doi.org/10.1021/acs.orglett.4c04834 http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/9375 |
| ISSN: | 1523-7060 1523-7052 |
| Appears in Collections: | JOURNAL ARTICLES |
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