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Larger pores via shorter pillars in flexible layer coordination networks

VAIDHYANATHAN, RAMANATHAN; Martens, Isaac; Lin, Jian-Bin; Iremonger, Simon S.; Shimizu, George K.H. (NRC Research Press, 2016-01)

Metal organic frameworks are porous coordination networks that offer tunable structures via modular synthetic routes. It is well established that zinc 3-amino-1,2,4-triazolate (ATz) forms structures with cationic layers. ...
Gas Transport Selectivity of Ultrathin, Nanoporous, Inorganic Membranes Made from Block Copolymer Templates

Greil, Stefanie; RAHMAN, ATIKUR; Liu, Mingzhao; Black, Charles T. (American Chemical Society, 2017-12)

We report the fabrication of ultrathin, nanoporous silicon nitride membranes made from templates of regular, nanoscale features in self-assembled block copolymer thin films. The inorganic membranes feature thicknesses less ...
Achieving current rectification ratios >= 10(5) across thin films of coordination polymer

PRASOON, ANUPAM; DHARA, BARUN; ROY, DEBASHREE; RANA, SHAMMI; BHAND, SUJIT; BALLAV, NIRMALYA (Royal Society of Chemistry, 2019-11)

Downsizing coordination polymers (CPs) to thin film configurations is a prerequisite for device applications. However, fabrication of thin films of CPs including metal-organic frameworks (MOFs) with reasonable electrical ...

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