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  • Strikingly diverse reactivity of structurally identical silylene and stannylene 
    PARVIN, NASRINA; DASGUPTA, RAJARSHI; PAL, SHIV; Sen, Sakya S.; KHAN, SHABANA (Royal Society of Chemistry, 2017-04)
    The reactivity of structurally identical silylene and stannylene [PhC(NtBu)2EN(SiMe3)2] (E = Si (1) and Sn (2)) towards coinage metals has been explored. While 1 has the propensity to form an adduct with coinage metals (4 ...
  • Cyclic Four-Membered Stanna Thio and Seleno Compounds from 2-Aminopyridinato Stannylenes 
    SEN, NILANJANA; PAL, SHIV; KHADE, VIKAS VILAS; KHAN, SHABANA (Wiley, 2019-11)
    In this paper, we have used 2-aminopyridinato ligands (1 and 2) to stabilize two four-coordinated tin(II) aminopyridinato compounds ([Sn{NPh(py)}(2)] (3) and [Sn{N(SiMe3)py}(2)] (4)) (py=pyridine) through a salt elimination ...
  • Heavier Tetrylenes as Single Site Catalysts 
    SEN, NILANJANA; KHAN, SHABANA (Wiley, 2021-04)
    An overview of the development of compounds with heavier low‐valent group 14 elements (known as tetrylenes) as single component catalyst for organic transformation has been provided. Compounds with heavier group 14 elements ...
  • Four-Coordinate Germylene and Stannylene and their Reactivity towards Se & Te 
    HOSSAIN, JABED; PARVIN, NASRINA; SHAH, BRIJ KUMAR; KHAN, SHABANA (Wiley, 2022-10)
    In this work, we have prepared a bulky ligand supported chlorogermylene (LGeCl) [L=C6H4-2-{C(Me)=NAr*}; Ar*=(2,6-bis(diphenylmethyl)-4-methylphenyl)] (2), chlorostannylene (LSnCl) (3), four-coordinate germylene (L2Ge) (4) ...