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The molecular spin state of NiII porphyrin, supported on a ferromagnetic Co surface, can be reversibly switched between spin‐off (S=0) and spin‐on (S=1) states upon coordination and decoordination of the gaseous ligand NH3, respectively (see picture). This finding clearly indicates the possible use of the system as a single‐molecule‐based magnetochemical sensor and in spintronics.
GOPALAKRISHNA, TULLIMILLI Y.
;
REDDY, J. SREEDHAR
;
ANAND, V. G.
(
Wiley
,
2013-02
)
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Author
ANAND, V. G. (1)
GOPALAKRISHNA, TULLIMILLI Y. (1)
REDDY, J. SREEDHAR (1)
Subject
2013 (1)
? interactions (1)
Antiaromaticity (1)
Conjugation (1)
Macrocycles (1)
Noncovalent interactions (1)
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Date Issued
2013 (1)