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Preparation of Germanium(IV) Monocation and Di-cation as Sigma Acceptor Ligand towards Transition Metals

P., BALAKRISHNA (2021-10)

Sigma acceptor type ligands are useful in transition metal catalysed Lewis acid catalysis. Placing of such type of ligands around the transition metal may increase the Lewis acidity of transition metals and interesting ...
Stabilization and Characterization of Bi(III) Compounds with peri-substituted Acenaphthene Based Ligands

KUNDU, ANKAN (2024-05)

Sigma acceptor ligands play a crucial role in transition metal catalyzed lewis acid catalysis. The presence of such ligands around the transition metal center can significantly tune the nature of lewis acidity of the ...
Bis (α-iminopyridine) Stabilized Dimeric Sb(II) and Bi(II) Tetra-cation : Bond Lability Based Reactivity

HALDAR, HRITWIK (2024-05)

Bis(alpha-iminopyridine) stabilized distibane tetra-cationic [1]2 and dibismuthane tetra-cationic [2]2 compounds have been synthesized. Both the compounds have been characterized in the solid-state using single-crystal ...
Investigation On Tetra-Cationic Heavier Di-Pnictanes

DAS, SATYABRATA (2025-05)

A thorough characterization of tetra-cationic dipnictane dimers (Sb = [1]2[OTf]4, Bi = [2]2[OTf]4) have been done, the role of solvent in their homolytic cleavage and differing stability in solution by UV-Visible Spectroscopy ...

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