An intramolecular phosphine-oxide stabilized germanium(iv) di-cation with enhanced Lewis acidity and catalytic applications

dc.contributor.author	KUMARI, AKANKSHA	en_US
dc.contributor.author	PEDDI, BALAKRISHNA	en_US
dc.contributor.author	Yildiz, Cem. B.	en_US
dc.contributor.author	MAJUMDAR, MOUMITA	en_US
dc.date.accessioned	2025-06-24T11:45:09Z
dc.date.available	2025-06-24T11:45:09Z
dc.date.issued	2025-05	en_US
dc.identifier.citation	Chemical Communications, 61(35), 6506-6509.	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	https://doi.org/10.1039/D5CC00250H	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10199
dc.description.abstract	This work reports the intramolecular phosphine-oxide stabilized tetra-coordinated germanium(IV) di-cation on an acenaphthene platform, 1iPrPO. Computational study shows that the positive charges and the acceptor orbitals are localized on the Ge site. 1iPrPO is Lewis super acidic, capable of catalysing hydrodefluorination reaction. 1iPrPO also catalyses hydrosilylation of electron-deficient aldehydes.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Chemistry	en_US
dc.subject	2025	en_US
dc.title	An intramolecular phosphine-oxide stabilized germanium(iv) di-cation with enhanced Lewis acidity and catalytic applications	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US