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Access to Bis-Silylene-Stabilized Group 13 Cations

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dc.contributor.author GHOSH, MOUSHAKHI en_US
dc.contributor.author PANWARIA, PRAKASH en_US
dc.contributor.author Tothadi, Srinu en_US
dc.contributor.author KHAN, SHABANA en_US
dc.date.accessioned 2025-07-07T10:32:08Z
dc.date.available 2025-07-07T10:32:08Z
dc.date.issued 2025-01 en_US
dc.identifier.citation Inorganic Chemistry, 64(02), 1110–1123. en_US
dc.identifier.issn 0020-1669 en_US
dc.identifier.issn 1520-510X en_US
dc.identifier.uri https://doi.org/10.1021/acs.inorgchem.4c04703 en_US
dc.identifier.uri http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10264
dc.description.abstract Herein, we report the isolation of pyridine moiety-functionalized SiNSi pincer-based bis-silylene ligand (1) and its reactivity toward various halide precursors (X = Br and I) of group 13 elements (M = Al, Ga, and In). This gave us straightforward access to the SiNSi pincer-coordinated group 13 cations (2–7). These complexes are duly characterized by single-crystal X-ray diffraction studies, multinuclear magnetic resonance spectroscopy (1H, 13C, and 29Si), and high-resolution mass spectrometry techniques. Their electronic properties were further analyzed with the help of quantum chemical calculations. en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.subject Anions en_US
dc.subject Aromatic compounds en_US
dc.subject Hydrocarbons en_US
dc.subject Mathematical methods en_US
dc.subject Molecular structure en_US
dc.subject 2025 en_US
dc.title Access to Bis-Silylene-Stabilized Group 13 Cations en_US
dc.type Article en_US
dc.contributor.department Dept. of Chemistry en_US
dc.identifier.sourcetitle Inorganic Chemistry en_US
dc.publication.originofpublisher Foreign en_US


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