dc.contributor.author |
GHOSH, MOUSHAKHI |
en_US |
dc.contributor.author |
PANWARIA, PRAKASH |
en_US |
dc.contributor.author |
Tothadi, Srinu |
en_US |
dc.contributor.author |
KHAN, SHABANA |
en_US |
dc.date.accessioned |
2025-07-07T10:32:08Z |
|
dc.date.available |
2025-07-07T10:32:08Z |
|
dc.date.issued |
2025-01 |
en_US |
dc.identifier.citation |
Inorganic Chemistry, 64(02), 1110–1123. |
en_US |
dc.identifier.issn |
0020-1669 |
en_US |
dc.identifier.issn |
1520-510X |
en_US |
dc.identifier.uri |
https://doi.org/10.1021/acs.inorgchem.4c04703 |
en_US |
dc.identifier.uri |
http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10264 |
|
dc.description.abstract |
Herein, we report the isolation of pyridine moiety-functionalized SiNSi pincer-based bis-silylene ligand (1) and its reactivity toward various halide precursors (X = Br and I) of group 13 elements (M = Al, Ga, and In). This gave us straightforward access to the SiNSi pincer-coordinated group 13 cations (2–7). These complexes are duly characterized by single-crystal X-ray diffraction studies, multinuclear magnetic resonance spectroscopy (1H, 13C, and 29Si), and high-resolution mass spectrometry techniques. Their electronic properties were further analyzed with the help of quantum chemical calculations. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
American Chemical Society |
en_US |
dc.subject |
Anions |
en_US |
dc.subject |
Aromatic compounds |
en_US |
dc.subject |
Hydrocarbons |
en_US |
dc.subject |
Mathematical methods |
en_US |
dc.subject |
Molecular structure |
en_US |
dc.subject |
2025 |
en_US |
dc.title |
Access to Bis-Silylene-Stabilized Group 13 Cations |
en_US |
dc.type |
Article |
en_US |
dc.contributor.department |
Dept. of Chemistry |
en_US |
dc.identifier.sourcetitle |
Inorganic Chemistry |
en_US |
dc.publication.originofpublisher |
Foreign |
en_US |