Reactivity of N-heterocyclic carbene, 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, towards heavier halogens (Br-2 and I-2)

dc.contributor.author	PAL, SHIV	en_US
dc.contributor.author	Manae, Meghna A.	en_US
dc.contributor.author	Khade, Vikas V.	en_US
dc.contributor.author	KHAN, SHABANA	en_US
dc.date.accessioned	2018-10-05T03:56:08Z
dc.date.available	2018-10-05T03:56:08Z
dc.date.issued	2018-07	en_US
dc.identifier.citation	Journal of the Indian Chemical Society. Vol. 95(7).	en_US
dc.identifier.issn	0019-4522	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1203
dc.identifier.uri	-	en_US
dc.description.abstract	In the present study, the stoichiometry variation of N-heterocyclic carbene (NHC), 1 with halogens (Br-2 and I-2) shows its reactivity pattern toward halogens. The NHC, 1 was treated with 2.0, 1.0 and 0.5 equivalent of I-2 to afford the complex 2, 3 and 4 respectively. In the same fashion, the treatment of 1 with 2.0 and 1.0 equivalent of Br-2 resulted in the formation of complexes 5 and 6.	en_US
dc.language.iso	en	en_US
dc.publisher	Indian Chemical Society	en_US
dc.subject	NHCs	en_US
dc.subject	X-ray crystallography	en_US
dc.subject	DFT	en_US
dc.subject	NHCs adducts	en_US
dc.subject	TOC-SEP-2018	en_US
dc.subject	2018	en_US
dc.title	Reactivity of N-heterocyclic carbene, 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, towards heavier halogens (Br-2 and I-2)	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Journal of the Indian Chemical Society	en_US
dc.publication.originofpublisher	Indian	en_US