A Metal Coordination Polymer Framework Governed by Heat of Hydration for Non-invasive Differentiation of Alkali Metal Series

Battu, Shateesh; KHAIRE, SIDDHI; BHAT, ZAHID MANZOOR; KOTTAICHAMY, ALAGAR RAJA; THIMMAPPA, RAVIKUMAR; THOTIYL, MUSTHAFA OTTAKAM; Itagi, Mahesh; Sannegowda, Lokesh Koodlur

DR Home
→
PUBLICATIONS & PATENTS
→
JOURNAL ARTICLES
→
View Item

dc.contributor.author	Battu, Shateesh	en_US
dc.contributor.author	Itagi, Mahesh	en_US
dc.contributor.author	BHAT, ZAHID MANZOOR	en_US
dc.contributor.author	KHAIRE, SIDDHI	en_US
dc.contributor.author	KOTTAICHAMY, ALAGAR RAJA	en_US
dc.contributor.author	Sannegowda, Lokesh Koodlur	en_US
dc.contributor.author	THIMMAPPA, RAVIKUMAR	en_US
dc.contributor.author	THOTIYL, MUSTHAFA OTTAKAM	en_US
dc.date.accessioned	2018-10-08T03:32:12Z
dc.date.available	2018-10-08T03:32:12Z
dc.date.issued	2018-10	en_US
dc.identifier.citation	Analytical Chemistry	en_US
dc.identifier.issn	0003-2700	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1217
dc.identifier.uri	https://doi.org/10.1021/acs.analchem.8b03541	en_US
dc.description.abstract	We illustrate that the extent of hydration and consequently the heat of hydration of alkali metal ions can be utilized to control their insertion/deinsertion chemistry in a redox active metal coordination polymer framework (CPF) electrode. The formal redox potential of CPF electrode for cation intercalation is inversely correlated to hydrated ionic radii, with clear distinction between the intercalation of ions across alkali metal series. This leads to non-invasive identification and differentiation of cations in the alkali metal series by utilizing a single sensing platform.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	2018	en_US
dc.subject	Metal Coordination Polymer Framework	en_US
dc.subject	Non-invasive Di fferentiation	en_US
dc.subject	TOC-SEP-2018	en_US
dc.title	A Metal Coordination Polymer Framework Governed by Heat of Hydration for Non-invasive Differentiation of Alkali Metal Series	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Analytical Chemistry	en_US
dc.publication.originofpublisher	Foreign	en_US