Bis(chlorogermyliumylidene) and its significant role in elusive reductive cyclization

MAJUMDAR, MOUMITA; RAUT, RAVINDRA K.; SAHOO, PADMINI; Kumar, Vikas

DR Home
→
PUBLICATIONS & PATENTS
→
JOURNAL ARTICLES
→
View Item

dc.contributor.author	MAJUMDAR, MOUMITA	en_US
dc.contributor.author	RAUT, RAVINDRA K.	en_US
dc.contributor.author	SAHOO, PADMINI	en_US
dc.contributor.author	Kumar, Vikas	en_US
dc.date.accessioned	2018-10-12T05:13:33Z
dc.date.available	2018-10-12T05:13:33Z
dc.date.issued	2018-10	en_US
dc.identifier.citation	Chemical Communications. Vol. 54(77).	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1298
dc.identifier.uri	https://doi.org/10.1039/c8cc06067c	en_US
dc.description.abstract	Bis(chlorogermyliumylidene) 2 has been strategically obtained within redox-active bis(-iminopyridine). Metal-free reduction of 2 followed by protonation led to elusive 2,3-di(pyridin-2-yl)piperazine with meso-stereoselectivity. Formation of persistent triplet diradicals upon reduction and isolation of piperazine stabilized Ge(ii) dication intermediates provide convincing evidence for the crucial role of [GeCl](+) units in reductive cyclization.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Chiral Piperazines	en_US
dc.subject	Transition-Metals	en_US
dc.subject	Radical Reactions	en_US
dc.subject	Chemistry	en_US
dc.subject	Coordination	en_US
dc.subject	Germylene	en_US
dc.subject	Dication	en_US
dc.subject	State	en_US
dc.subject	Germyliumylidene	en_US
dc.subject	Diradicals	en_US
dc.subject	TOC-OCT-2018	en_US
dc.subject	2018	en_US
dc.title	Bis(chlorogermyliumylidene) and its significant role in elusive reductive cyclization	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US