Tin(ii) chloride assisted synthesis of N-protected γ-amino β-keto esters through semipinacol rearrangement

dc.contributor.author	BANDYOPADHYAY, ANUPAM	en_US
dc.contributor.author	Agrawal, Neha	en_US
dc.contributor.author	MALI, SACHITANAND M.	en_US
dc.contributor.author	JADHAV, SANDIP V.	en_US
dc.contributor.author	GOPI, HOSAHUDYA N.	en_US
dc.date.accessioned	2019-01-21T10:29:25Z
dc.date.available	2019-01-21T10:29:25Z
dc.date.issued	2010-11	en_US
dc.identifier.citation	Organic and Biomolecular Chemistry, (21).	en_US
dc.identifier.issn	1477-0520	en_US
dc.identifier.issn	1477-0539	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1493
dc.identifier.uri	https://doi.org/10.1039/C0OB00199F	en_US
dc.description.abstract	A facile synthetic route for the preparation of N-protected γ-amino β-keto esters from amino aldehydes and ethyl diazoacetate is described. The two component coupling is facilitated by tin(II) chloride followed by semipinacol rearrangement leading to the product in quantitative yield. The reaction is mild, instantaneous and compatible with Boc-, Fmoc- and Cbz-amino protecting groups.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	chloride	en_US
dc.subject	amino aldehydes	en_US
dc.subject	2010	en_US
dc.title	Tin(ii) chloride assisted synthesis of N-protected γ-amino β-keto esters through semipinacol rearrangement	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Organic and Biomolecular Chemistry	en_US
dc.publication.originofpublisher	Foreign	en_US