Metal‐Assisted Cyclomerization of N‐Confused Dipyrrins into Expanded Norroles

dc.contributor.author	GADEKAR, SANTOSH C.	en_US
dc.contributor.author	REDDY, BADDIGAM KIRAN	en_US
dc.contributor.author	ANAND, V. G.	en_US
dc.date.accessioned	2019-02-14T05:00:44Z
dc.date.available	2019-02-14T05:00:44Z
dc.date.issued	2013-07	en_US
dc.identifier.citation	Angewandte Chemie International Edition, 52(28),	en_US
dc.identifier.issn	1433-7851	en_US
dc.identifier.issn	1521-3773	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1620
dc.identifier.uri	https://doi.org/10.1002/anie.201303184	en_US
dc.description.abstract	Neoconfusion: In contrast to metal ligation by dipyrrin (see scheme, left), N‐confused dipyrrin undergoes cyclomerization with various metal salts to form NCNCNC and NCNCNCNC expanded norroles (see scheme, right), novel isomers of 24 π rosarin and 32 π octaphyrin with C–N linked bipyrrole units with near‐planar conformations in the solid state. They also exhibit paratropic ring‐current effects typical of antiaromatic porphyrinoids.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	Metal‐Assisted	en_US
dc.subject	Cyclomerization	en_US
dc.subject	N‐Confused Dipyrrins	en_US
dc.subject	Expanded Norroles	en_US
dc.subject	2013	en_US
dc.title	Metal‐Assisted Cyclomerization of N‐Confused Dipyrrins into Expanded Norroles	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Angewandte Chemie International Edition	en_US
dc.publication.originofpublisher	Foreign	en_US