Porphyrin metalation providing an example of a redox reaction facilitated by a surface reconstruction

Jung, Thomas A.; Wackerlin, Christian; Siewert, Dorota; BALLAV, NIRMALYA; Nowakowski, Jan; Girovsky, Jan

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dc.contributor.author	Nowakowski, Jan	en_US
dc.contributor.author	Wackerlin, Christian	en_US
dc.contributor.author	Girovsky, Jan	en_US
dc.contributor.author	Siewert, Dorota	en_US
dc.contributor.author	Jung, Thomas A.	en_US
dc.contributor.author	BALLAV, NIRMALYA	en_US
dc.date.accessioned	2019-02-14T05:01:22Z
dc.date.available	2019-02-14T05:01:22Z
dc.date.issued	2013-02	en_US
dc.identifier.citation	Chemical Communications, 49(23), 2347-2349.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1623
dc.identifier.uri	https://doi.org/10.1039/C3CC39134E	en_US
dc.description.abstract	he presence of an oxygen reconstruction on the Cu(001) surface results in the self-metalation of 5,10,15,20-tetraphenylporphyrin (2HTPP) below room temperature (at -285 K), in contrast to 2 HTPP on the bare Cu(001) substrate, where a temperature of -450 K is required. This study demonstrates the decisive impact of a surface reconstruction on the redox reaction in the solvent-free ultra-high vacuum environment.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Porphyrin metalation	en_US
dc.subject	Redox reaction	en_US
dc.subject	Surface reconstruction	en_US
dc.subject	Oxygen reconstruction	en_US
dc.subject	2013	en_US
dc.title	Porphyrin metalation providing an example of a redox reaction facilitated by a surface reconstruction	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US