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Hypervalent Iodine Mediated Synthesis of C-2 Deoxy Glycosides and Amino Acid Glycoconjugates

Hypervalent Iodine Mediated Synthesis of C-2 Deoxy Glycosides and Amino Acid Glycoconjugates

Islam, Maidul; Tirukoti, Nishanth D.; NANDI, SHYAMAPADA; HOTHA, SRINIVAS
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1937
https://doi.org/10.1021/jo500465m
Date: 2014-05


Abstract:

A simple, efficient, and practical method for the synthesis of C-2 deoxy-2-iodo glycoconjugates in self-assembled structures was found using PhI(OCOR)2. 2-Iodo glycoserinyl esters were intramolecularly converted into 2-iodo serinyl glycosides which upon dehalogenation gave C-2 deoxy amino acid glycoconjugates.

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