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Controlling the Dimensionality of On-Surface Coordination Polymers via Endo- or Exoligation

Show simple item record Shchyrba, Aneliia en_US W. ckerlin, Christian en_US Nowakowski, Jan en_US Nowakowska, Sylwia en_US Nijs, Thomas en_US Martens, Susanne C. en_US Kleibert, Armin en_US Stohr, Meike en_US BALLAV, NIRMALYA en_US Jung, Thomas A. en_US Gade, Lutz H. en_US 2019-02-25T09:01:36Z 2019-02-25T09:01:36Z 2014-07 en_US
dc.identifier.citation Journal of the American Chemical Society, 136(26), 9355-9363. en_US
dc.identifier.issn Feb-63 en_US
dc.identifier.issn 1520-5126 en_US
dc.identifier.uri en_US
dc.description.abstract The formation of on-surface coordination polymers is controlled by the interplay of chemical reactivity and structure of the building blocks, as well as by the orientating role of the substrate registry. Beyond the predetermined patterns of structural assembly, the chemical reactivity of the reactants involved may provide alternative pathways in their aggregation. Organic molecules, which are transformed in a surface reaction, may be subsequently trapped via coordination of homo- or heterometal adatoms, which may also play a role in the molecular transformation. The amino-functionalized perylene derivative, 4,9-diaminoperylene quinone-3,10-diimine (DPDI), undergoes specific levels of dehydrogenation (−1 H2 or −3 H2) depending on the nature of the present adatoms (Fe, Co, Ni or Cu). In this way, the molecule is converted to an endo- or an exoligand, possessing a concave or convex arrangement of ligating atoms, which is decisive for the formation of either 1D or 2D coordination polymers. en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.subject Controlling the Dimensionality en_US
dc.subject Polymers en_US
dc.subject Organic molecules en_US
dc.subject Coordination polymers en_US
dc.subject 2014 en_US
dc.title Controlling the Dimensionality of On-Surface Coordination Polymers via Endo- or Exoligation en_US
dc.type Article en_US
dc.contributor.department Dept. of Chemistry en_US
dc.identifier.sourcetitle Journal of the American Chemical Society en_US
dc.publication.originofpublisher Foreign en_US

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