A cationic copper(i) iodide cluster MOF exhibiting unusual ligand assisted thermochromism

dc.contributor.author	Yadav, Ashok	en_US
dc.contributor.author	Srivastava, Anant Kumar	en_US
dc.contributor.author	Balamurugana, Ayyakkalai	en_US
dc.contributor.author	BOOMISHANKAR, RAMAMOORTHY	en_US
dc.date.accessioned	2019-02-25T09:01:37Z
dc.date.available	2019-02-25T09:01:37Z
dc.date.issued	2014-04	en_US
dc.identifier.citation	Dalton Transactions, 43(22), 8166-8169.	en_US
dc.identifier.issn	1477-9226	en_US
dc.identifier.issn	1477-9234	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1948
dc.identifier.uri	https://doi.org/10.1039/C4DT00050A	en_US
dc.description.abstract	BBy employing a tridentate thiophosphoramide ligand, [(NHAQ)3P[double bond, length as m-dash]S] (AQ = 3-quinolinyl), a cationic MOF, 1 {[Cu6I5(L1)2](OH)·3DMF·2.5MeOH}n, was synthesized. Photo-physical studies on the 2D-MOF 1 showed an unusual thermochromic behaviour emitting a blue fluorescence at 298 K due to the AQ chromophore and an orange-yellow phosphorescence at 77 K due to the [Cu6I5]+ unit.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Cationic copper(I) iodide cluster	en_US
dc.subject	MOF exhibiting unusual	en_US
dc.subject	Assisted thermochromism	en_US
dc.subject	Coordination compounds	en_US
dc.subject	2014	en_US
dc.title	A cationic copper(i) iodide cluster MOF exhibiting unusual ligand assisted thermochromism	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Dalton Transactions	en_US
dc.publication.originofpublisher	Foreign	en_US