Palladium-catalyzed cyclization of benzamides with arynes: application to the synthesis of phenaglydon and N-methylcrinasiadine

JEGANMOHAN, MASILAMANI; Pimparkar, Sandeep

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Palladium-catalyzed cyclization of benzamides with arynes: application to the synthesis of phenaglydon and N-methylcrinasiadine

Pimparkar, Sandeep; JEGANMOHAN, MASILAMANI

URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1964 https://doi.org/10.1039/C4CC05252H Date: 2014-08

Abstract:

N-Methyl or methoxy benzamides reacted with benzynes in the presence of Pd(OAc)2, organic acid and K2S2O8 in CH3CN yielding tricyclic phenanthridinone derivatives in good yields.

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Palladium-catalyzed cyclization of benzamides with arynes: application to the synthesis of phenaglydon and N-methylcrinasiadine

Palladium-catalyzed cyclization of benzamides with arynes: application to the synthesis of phenaglydon and N-methylcrinasiadine

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