Guest driven structural transformation studies of a luminescent metal-organic framework

GHOSH, SUJIT K.; Manna, Biplab; SINGH, S.

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dc.contributor.author	Manna, Biplab	en_US
dc.contributor.author	SINGH, S.	en_US
dc.contributor.author	GHOSH, SUJIT K.	en_US
dc.date.accessioned	2019-02-25T09:02:10Z
dc.date.available	2019-02-25T09:02:10Z
dc.date.issued	2014-11	en_US
dc.identifier.citation	Journal of Chemical Sciences, 126(5), 1417-1422.	en_US
dc.identifier.issn	0974-3626	en_US
dc.identifier.issn	0973-7103	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1978
dc.identifier.uri	https://doi.org/10.1007/s12039-014-0704-y	en_US
dc.description.abstract	A two-dimensional (2D) porous metal-organic framework (MOF) [{Zn2(L) 4(OTf) 4}.2(DCM).xG]n (1 ? G) (OTf = trifluoro methane sulfonate, DCM = Dichloromethane, L (1, 4-bis (4-pyridyl)-2, 3-diaza-1, 3-butadiene) synthesized at room temperature. Free guests DCM were encapsulated in the pores of the MOF. On air drying the MOF loses free DCM molecules and changed its structure in a crystal to crystal manner to produce compound 1 [{Zn(L)2(OTf)2}.XG]n(1). This guest-induced breathing of the framework was also supported from PXRD patterns. Solid state photoluminescence properties of the dynamic MOF were studied at room temperature.	en_US
dc.language.iso	en	en_US
dc.publisher	Indian Academy of Sciences	en_US
dc.subject	Guest driven	en_US
dc.subject	Structural transformation	en_US
dc.subject	luminescent metal	en_US
dc.subject	Organic framework	en_US
dc.subject	Photoluminescence properties	en_US
dc.subject	2014	en_US
dc.title	Guest driven structural transformation studies of a luminescent metal-organic framework	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Journal of Chemical Sciences	en_US
dc.publication.originofpublisher	Indian	en_US