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Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal-organic framework

Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal-organic framework

Manna, Biplab; DESAI, AAMOD V.; Kumar, Naveen; Karmakar, Avishek; GHOSH, SUJIT K.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2196
https://doi.org/10.1039/C5CE00139K
Date: 2015-03


Abstract:

A three dimensional (3D) cationic Metal-Organic Framework (MOF) has been fabricated from a neutral N-donor ligand and Cd(ClO4)2. The cationic MOF shows guest triggered inherent dynamic behaviour at room temperature. A single-crystal-to-single-crystal (SCSC) transformation experiment enabled the guest dependent structural dynamism to be well understood. The framework also displays facile anion exchange behaviour and anion dependent structural dynamism.

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