Oxidative Cross-Coupling of Two Different Phenols: An Efficient Route to Unsymmetrical Biphenols

More, Nagnath Yadav; JEGANMOHAN, MASILAMANI

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dc.contributor.author	More, Nagnath Yadav	en_US
dc.contributor.author	JEGANMOHAN, MASILAMANI	en_US
dc.date.accessioned	2019-03-15T11:24:15Z
dc.date.available	2019-03-15T11:24:15Z
dc.date.issued	2015-06	en_US
dc.identifier.citation	Organic Letters, 17 (12), 3042-3045.	en_US
dc.identifier.issn	1523-7060	en_US
dc.identifier.issn	1523-7052	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2209
dc.identifier.uri	https://doi.org/10.1021/acs.orglett.5b01324	en_US
dc.description.abstract	An efficient synthesis of unsymmetrical biphenols via the oxidative cross-coupling of two different phenols in the presence of K2S2O8 and Bu4N+·HSO3– (10 mol %) in CF3COOH at ambient conditions is described. 1:1 Cross-coupling of substituted phenols with naphthols and 1:2 cross-coupling of naphthols with phenol are also disclosed. By using Bu4N+·HSO3–, the homocoupling of phenols or naphthols was controlled. In these reactions, the ortho C–H bond of two different phenols and the ortho and para C–H bond of phenols were coupled together.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Oxidative Cross-Coupling	en_US
dc.subject	Two Different Phenols	en_US
dc.subject	Efficient Route	en_US
dc.subject	Unsymmetrical Biphenols	en_US
dc.subject	C-H bond of phenols	en_US
dc.subject	2015	en_US
dc.title	Oxidative Cross-Coupling of Two Different Phenols: An Efficient Route to Unsymmetrical Biphenols	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Organic Letters	en_US
dc.publication.originofpublisher	Foreign	en_US