The Rearrangement of Peroxides for the Construction of Fluorophoric 1,4-Benzoxazin-3-one Derivatives

GNANAPRAKASAM, BOOPATHY; CHAUDHARY, ATUL; KUMAR, VISHNUPRIYA; CHAUDHARI, MORESHWAR B.

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dc.contributor.author	CHAUDHARI, MORESHWAR B.	en_US
dc.contributor.author	CHAUDHARY, ATUL	en_US
dc.contributor.author	KUMAR, VISHNUPRIYA	en_US
dc.contributor.author	GNANAPRAKASAM, BOOPATHY	en_US
dc.date.accessioned	2019-03-26T10:01:40Z
dc.date.available	2019-03-26T10:01:40Z
dc.date.issued	2019-02	en_US
dc.identifier.citation	Organic Letters, 21(06),1617-1621.	en_US
dc.identifier.issn	1523-7060	en_US
dc.identifier.issn	1523-7052	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2407
dc.identifier.uri	https://doi.org/10.1021/acs.orglett.9b00155	en_US
dc.description.abstract	An unprecedented skeletal rearrangement of 3-(tert-butylperoxy)indolin-2-one using a tin catalyst has been developed. This rearrangement is highly selective to afford a series of fluorophoric (Z)-2-arylidene and alkylidene-An unprecedented skeletal rearrangement of 3-(tert-butylperoxy)indolin-2-one using a tin catalyst has been developed. This rearrangement is highly selective to afford a series of fluorophoric (Z)-2-arylidene and alkylidene-2H-benzo[b][1,4]oxazin-3(4H)-one derivatives in good to excellent yield. In contrast with Sn(OTf)2, the reaction of 3-(tert-butylperoxy)indolin-2-one derivatives with FeCl3 afforded the Hock fragmentation product via C–C bond cleavage.	en_US
dc.language.iso	en	en_US
dc.publisher	American Chemical Society	en_US
dc.subject	Chemistry	en_US
dc.subject	TOC-MAR-2019	en_US
dc.subject	2019	en_US
dc.title	The Rearrangement of Peroxides for the Construction of Fluorophoric 1,4-Benzoxazin-3-one Derivatives	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Organic Letters	en_US
dc.publication.originofpublisher	Foreign	en_US