A pyramidal Tin(II) dication and its reactivity studies

MAJUMDAR, MOUMITA; RAUT, RAVINDRA K.

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dc.contributor.author	RAUT, RAVINDRA K.	en_US
dc.contributor.author	MAJUMDAR, MOUMITA	en_US
dc.date.accessioned	2019-04-25T07:00:12Z
dc.date.available	2019-04-25T07:00:12Z
dc.date.issued	2019-05	en_US
dc.identifier.citation	Journal of Organometallic Chemistry, 887, 18-23.	en_US
dc.identifier.issn	0022-328X	en_US
dc.identifier.issn	1872-8561	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2451
dc.identifier.uri	https://doi.org/10.1016/j.jorganchem.2019.02.019	en_US
dc.description.abstract	An acyclic flexible bis(α-iminopyridine) ligand has been employed for the stabilization of chlorostannyliumylidene and a tin(II) dication. The syntheses involve the abstraction of chloride from the tin dichloride precursor using trimethylsilyl trifluoromethane sulfonate. The apically disposed tin(II) dication exhibits electrophilic behaviour and undergoes transmetallation reaction with GeCl2.dioxane resulting in stabilizing the Ge(II) dication. All the compounds have been characterized by NMR techniques and single crystal X-ray crystallography.	en_US
dc.language.iso	en	en_US
dc.publisher	Elsevier B.V.	en_US
dc.subject	Tin(II) (poly)cation	en_US
dc.subject	s-character	en_US
dc.subject	Electrophilic	en_US
dc.subject	Nucleophilic	en_US
dc.subject	Transmetallation	en_US
dc.subject	Inert pair effect	en_US
dc.subject	TOC-APR-2019	en_US
dc.subject	2019	en_US
dc.title	A pyramidal Tin(II) dication and its reactivity studies	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Journal of Organometallic Chemistry	en_US
dc.publication.originofpublisher	Foreign	en_US