p-Nitrophenyl carbonate promoted ring-opening reactions of DBU and DBN affording lactam carbamates

dc.contributor.author	VANGALA, MADHURI	en_US
dc.contributor.author	Shinde, Ganesh P.	en_US
dc.date.accessioned	2019-04-29T10:14:36Z
dc.date.available	2019-04-29T10:14:36Z
dc.date.issued	2016-09	en_US
dc.identifier.citation	Beilstein Journal of Organic Chemistry, 12(1), 2086-2092.	en_US
dc.identifier.issn	1860-5397	en_US
dc.identifier.issn	1860-5397	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2675
dc.identifier.uri	https://doi.org/10.3762/bjoc.12.197	en_US
dc.description.abstract	The amidine bases DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) and DBN (1,5-diazabicyclo[4.3.0]non-5-ene) display nucleophilic behaviour towards highly electrophilic p-nitrophenyl carbonate derivatives with ring opening of the bicyclic ring to form corresponding substituted ε-caprolactam and γ-lactam derived carbamates. This simple method presents a unified strategy to synthesize structurally diverse ε-caprolactam and γ-lactam compounds with a large substrate scope.	en_US
dc.language.iso	en	en_US
dc.publisher	Beilstein-Institute	en_US
dc.subject	Carbonates	en_US
dc.subject	DBN	en_US
dc.subject	DBU	en_US
dc.subject	lactams	en_US
dc.subject	p-nitrophenyl	en_US
dc.subject	Organic bases	en_US
dc.subject	2016	en_US
dc.title	p-Nitrophenyl carbonate promoted ring-opening reactions of DBU and DBN affording lactam carbamates	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Beilstein Journal of Organic Chemistry	en_US
dc.publication.originofpublisher	Foreign	en_US