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Metal assisted cyclomerization of benzodipyrrins into expanded norroles, aza-heptalene and acyclic dimers

Metal assisted cyclomerization of benzodipyrrins into expanded norroles, aza-heptalene and acyclic dimers

GADEKAR, SANTOSH C.; REDDY, BADDIGAM K.; PANCHAL, SANTOSH P.; ANAND, V. G.
URI: http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2678
https://doi.org/10.1039/C5CC10356H
Date: 2016-03


Abstract:

Benzofused dipyrrins react with metal salt copper(II) acetate to predominantly yield a cyclodimer along with a cyclotrimer. N-confused monobenzo-dipyrrin cyclomerized to trioxo-expanded norrole 13a and an acyclic dimer 14 whereas doubly N-confused monobenzo and dibenzo-dipyrrins yielded aza-heptalene 15 and an acyclic dimer 16.

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