Harnessing Lewis acidic open metal sites of metal organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane

Babarao, Ravichandar; DESAI, AAMOD V.; GHOSH, SUJIT K.; Yin, Yuefeng; Mukherjee, Soumya; Manna, Biplab; Krishna, Rajamani

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dc.contributor.author	Mukherjee, Soumya	en_US
dc.contributor.author	Manna, Biplab	en_US
dc.contributor.author	DESAI, AAMOD V.	en_US
dc.contributor.author	Yin, Yuefeng	en_US
dc.contributor.author	Krishna, Rajamani	en_US
dc.contributor.author	Babarao, Ravichandar	en_US
dc.contributor.author	GHOSH, SUJIT K.	en_US
dc.date.accessioned	2019-04-29T10:15:08Z
dc.date.available	2019-04-29T10:15:08Z
dc.date.issued	2016-05	en_US
dc.identifier.citation	Chemical Communications, 52(53), 8215-8218.	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.issn	1364-548X	en_US
dc.identifier.uri	http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2698
dc.identifier.uri	https://doi.org/10.1039/C6CC03015G	en_US
dc.description.abstract	π-Complexation triggered Lewis acid–base interactions between open metal sites (OMS) of metal–organic frameworks (MOFs), and π-e− rich adsorptive benzene (Bz) is exploited to establish M-MOF-74 as the best Bz-selective MOF sorbent, marking the first report of utilizing OMS behind benzene/cyclohexane separation; a key advance from the energy-economy standpoint of industrial separation.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Harnessing Lewis acidic	en_US
dc.subject	Organic frameworks	en_US
dc.subject	Benzene sorption	en_US
dc.subject	Cyclohexane	en_US
dc.subject	2016	en_US
dc.title	Harnessing Lewis acidic open metal sites of metal organic frameworks: the foremost route to achieve highly selective benzene sorption over cyclohexane	en_US
dc.type	Article	en_US
dc.contributor.department	Dept. of Chemistry	en_US
dc.identifier.sourcetitle	Chemical Communications	en_US
dc.publication.originofpublisher	Foreign	en_US